鲁统部 教授

 

天津理工大学

为了应对全球能源供应的紧张以及温室气体排放导致的气候变化，人们日益加强了对水分解 (water splitting) 和二氧化碳的还原 (CO₂ reduction) 的研究。金属有机骨架 (Metal Organic Framework, MOF) 材料具有明确的结构以及不饱和的金属配位催化位点，因此能帮助我们更好地认识结构与催化活性之间的关系。此外，还可以通过改变 MOF 的结构以及在 MOF 的孔道或框架内对分子／纳米粒子进行后修饰等做法来优化 MOF 的催化活性。但是，在强酸或强碱性的催化条件下，MOF 可能被分解并释放出真正起到催化作用的金属离子或金属氧化物；因此，必须确认 MOF 在催化后依然稳定存在，以确保它们是实际的催化剂。

该合辑中的论文如下：

• Perspectives on metal–organic frameworks with intrinsic electrocatalytic activity
  Marcello B. Solomon, Tamara L. Church and Deanna M. D'Alessandro

  This highlight article focuses on the rapidly emerging area of electrocatalytic metal–organic frameworks (MOFs) with a particular emphasis on those systems displaying intrinsic activity.

  

  通讯作者：Deanna M. D'Alessandro(悉尼大学)

  CrystEngComm, 2017,19, 4049-4065

  https://doi.org/10.1039/C7CE00215G

• Metal–organic frameworks with Lewis acidity: synthesis, characterization, and catalytic applications
  Zhigang Hu and Dan Zhao

  In this highlight, we review the recent development in the design and synthesis of metal–organic frameworks with Lewis acidity, the characterization techniques of Lewis acid sites, and their applications in heterogeneous catalysis.

  

  通讯作者：赵丹(新加坡国立大学)

  CrystEngComm, 2017,19, 4066-4081

  https://doi.org/10.1039/C6CE02660E

• Understanding metal–organic frameworks for photocatalytic solar fuel production
  J. G. Santaclara, F. Kapteijn, J. Gascon and M. A. van der Veen

  The fascinating chemical and physical properties of MOFs have recently stimulated exploration of their application for photocatalysis. Design guidelines for these materials in photocatalytic solar fuel generation can be developed by applying the right spectroscopic tools.

  

  通讯作者：J. Gascon(代尔夫特理工大学), M. A. van der Veen(代尔夫特理工大学)

  CrystEngComm, 2017,19, 4118-4125

  https://doi.org/10.1039/C7CE00006E

• Polymorphs of a copper coordination compound: interlinking active sites enhance the electrocatalytic activity of the coordination polymer compared to the coordination complex
  Pandi Muthukumar, Mehboobali Pannipara, Abdullah G. Al-Sehemi, Dohyun Moon and Savarimuthu Philip Anthony

  A copper coordination polymer exhibits highly enhanced HER activity in neutral medium compared to a coordination complex with a similar coordination environment.

  

  通讯作者：Dohyun Moon(Pohang 加速实验室), Savarimuthu Philip Anthony(SASTRA Deemed University)

  CrystEngComm, 2020,22, 425-429

  https://doi.org/10.1039/C9CE01698H

  
  

• Trinuclear Ni(II) oriented highly dense packing and π-conjugation degree of metal–organic frameworks for efficient water oxidation
  Zhi-Min Zhai, Xiao-Gang Yang, Zhao-Tong Yang, Xiao-Min Lu and Lu-Fang Ma

  Trinuclear nickel cluster based MOF shows highly denser crystal packing and π-conjugation degree as well as outstanding OER performance with an overpotential of 270 mV at 10 mA cm−2.

  

  通讯作者：杨晓刚(洛阳师范大学)

  CrystEngComm, 2019,21, 5862-5866

  https://doi.org/10.1039/C9CE00944B

• Two metal–organic frameworks sharing the same basic framework show distinct interpenetration degrees and different performances in CO2 catalytic conversion
  Pei-Zhou Li, Xiao-Jun Wang, Jia Liu, Jie Liang, Jie Yi Jalyn Chen and Yanli Zhao

  Two metal–organic frameworks having the same basic framework but different interpenetration degrees show different catalytic activities in CO2 cycloaddition reactions.

  

  通讯作者：Yanli Zhao(南洋理工大学)

  CrystEngComm, 2017,19, 4157-4161

  https://doi.org/10.1039/C7CE00100B

• Nanostructured ZnO as a structural template for the growth of ZIF-8 with tunable hierarchical porosity for CO2 conversion
  Min-Kyeong Kim, Daeok Kim, Jung Yoon Seo, Onur Buyukcakir and Ali Coskun

  We report a new approach to introduce hierarchical porosity into ZIF-8 by using three-dimensional nanostructured porous ZnO as a structural template.

  

  通讯作者：Ali Coskun(韩国科学技术院)

  CrystEngComm, 2017,19, 4147-4151

  https://doi.org/10.1039/C6CE02549H

• Covalently anchoring cobalt phthalocyanine on zeolitic imidazolate frameworks for efficient carbon dioxide electroreduction
  Zhongjie Yang, Xiaofei Zhang, Chang Long, Shuhao Yan, Yanan Shi, Jianyu Han, Jing Zhang, Pengfei An, Lin Chang and Zhiyong Tang

  Transformation of CO2 into fuels has drawn great attention due to increasing carbon emission in recent years.

  

  通讯作者：唐智勇(国家纳米科学中心)

  CrystEngComm, 2020,22, 1619-1624

  https://doi.org/10.1039/C9CE01517E

• The Co2+/Ni2+ ion-mediated formation of a topochemically converted copper coordination polymer: structure-dependent electrocatalytic activity
  Pandi Muthukumar, Dohyun Moon and Savarimuthu Philip Anthony

  The presence of Co2+/Ni2+ ions strongly influenced the formation of copper coordination polymers that showed a structure-dependent hydrogen evolution reaction catalytic activity.

  

  通讯作者：Dohyun Moon(Pohang 加速实验室), Savarimuthu Philip Anthony(SASTRA Deemed University)

  CrystEngComm, 2019,21, 6552-6557

  https://doi.org/10.1039/C9CE01178A

• Metal–organic frameworks based on tetraphenylpyrazine-derived tetracarboxylic acid for electrocatalytic hydrogen evolution reaction and NAC sensing
  Tao Wang, Kun Huang, Mengni Peng, Xianglin Li, Defang Han, Linhai Jing and Dabin Qin

  Tetraphenylpyrazine-derived tetracarboxylic acid-based new MOFs and their promising applications in the electrocatalytic hydrogen evolution reaction.

  

  通讯作者：Kun Huang(西华师范大学), Dabin Qin(西华师范大学)

  CrystEngComm, 2019,21, 494-501

  https://doi.org/10.1039/C8CE01868E

• Synthesis of core–shell ZIF-67@Co-MOF-74 catalyst with controllable shell thickness and enhanced photocatalytic activity for visible light-driven water oxidation
  Changyan Guo, Jia Guo, Yonghong Zhang, Di Wang, Li Zhang, Yuan Guo, Wenlan Ma and Jide Wang

  Core–shell ZIF-67@Co-MOF-74 catalysts with improved photocatalytic properties were synthesized via the ligand exchange method.

  

  通讯作者：Yonghong Zhang(新疆大学), Jide Wang(新疆大学)

  CrystEngComm, 2018,20, 7659-7665

  https://doi.org/10.1039/C8CE01266K

• Polyoxometalate-based metal–organic framework loaded with an ultra-low amount of Pt as an efficient electrocatalyst for hydrogen production
  Haiyue Peng, Xiaojian Yang, Yuanyuan Ma, Jianing Liu, Yonghui Wang, Huaqiao Tan and Yangguang Li

  A low-Pt content polyoxometalate-based metal–organic framework (Pt@POMOF-1/KB) displays a highly efficient performance towards the hydrogen evolution reaction.

  

  通讯作者：Yuanyuan Ma(东北师范大学), Yonghui Wang(东北师范大学), 李阳光(东北师范大学)

  CrystEngComm, 2018,20, 5387-5394

  https://doi.org/10.1039/C8CE01151F

• Improved conductivity of a new Co(II)-MOF by assembled acetylene black for efficient hydrogen evolution reaction
  Wei Zhou, Ya-Pan Wu, Xiao Wang, Jun-Wu Tian, Dan-Dan Huang, Jun Zhao, Ya-Qian Lan and Dong-Sheng Li

  Metal–organic frameworks (MOFs) incorporating different metal nanoparticles or conductive additives are expected to possess desirable catalytic performance.

  

  通讯作者：Chan Beum Park(三峡大学), 李东升(三峡大学)

  CrystEngComm, 2018,20, 4804-4809

  https://doi.org/10.1039/C8CE00921J

来源：RSC英国皇家化学会